What I am looking for is ORDERS are sent to the saved "default" email, and customers sending in an INQUIRY to the "conact us" feature go to another email. Is that possible?
You could use two different emails for this. The contact us form needs to use the default email account but orders completed for example does not. You could change the email used for orders completed from Administration area -> Content Management -> Message Templates, in there find OrderCompleted.CustomerNotification, click edit and below the email body you will see Email account dropdown. Just select the email account you want from there.